A supermolecular building approach for the design and construction of metal–organic frameworks

Handle URI:
http://hdl.handle.net/10754/550725
Title:
A supermolecular building approach for the design and construction of metal–organic frameworks
Authors:
Guillerm, Vincent ( 0000-0003-3460-223X ) ; Kim, Dongwook; Eubank, Jarrod F.; Luebke, Ryan ( 0000-0002-1285-3321 ) ; Liu, Xinfang; Adil, Karim; Lah, Myoung Soo; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
In this review, we describe two recently implemented conceptual approaches facilitating the design and deliberate construction of metal–organic frameworks (MOFs), namely supermolecular building block (SBB) and supermolecular building layer (SBL) approaches. Our main objective is to offer an appropriate means to assist/aid chemists and material designers alike to rationally construct desired functional MOF materials, made-to-order MOFs. We introduce the concept of net-coded building units (net-cBUs), where precise embedded geometrical information codes uniquely and matchlessly a selected net, as a compelling route for the rational design of MOFs. This concept is based on employing pre-selected 0-periodic metal–organic polyhedra or 2-periodic metal–organic layers, SBBs or SBLs respectively, as a pathway to access the requisite net-cBUs. In this review, inspired by our success with the original rht-MOF, we extrapolated our strategy to other known MOFs via their deconstruction into more elaborate building units (namely polyhedra or layers) to (i) elucidate the unique relationship between edge-transitive polyhedra or layers and minimal edge-transitive 3-periodic nets, and (ii) illustrate the potential of the SBB and SBL approaches as a rational pathway for the design and construction of 3-periodic MOFs. Using this design strategy, we have also identified several new hypothetical MOFs which are synthetically targetable.
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3); Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division
Citation:
A supermolecular building approach for the design and construction of metal–organic frameworks 2014, 43 (16):6141 Chem. Soc. Rev.
Publisher:
Royal Society of Chemistry
Journal:
Chem. Soc. Rev.
Issue Date:
10-Jul-2014
DOI:
10.1039/C4CS00135D
Type:
Article
ISSN:
0306-0012; 1460-4744
Additional Links:
http://xlink.rsc.org/?DOI=C4CS00135D
Appears in Collections:
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorGuillerm, Vincenten
dc.contributor.authorKim, Dongwooken
dc.contributor.authorEubank, Jarrod F.en
dc.contributor.authorLuebke, Ryanen
dc.contributor.authorLiu, Xinfangen
dc.contributor.authorAdil, Karimen
dc.contributor.authorLah, Myoung Sooen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2015-04-27T16:28:46Zen
dc.date.available2015-04-27T16:28:46Zen
dc.date.issued2014-07-10en
dc.identifier.citationA supermolecular building approach for the design and construction of metal–organic frameworks 2014, 43 (16):6141 Chem. Soc. Rev.en
dc.identifier.issn0306-0012en
dc.identifier.issn1460-4744en
dc.identifier.doi10.1039/C4CS00135Den
dc.identifier.urihttp://hdl.handle.net/10754/550725en
dc.description.abstractIn this review, we describe two recently implemented conceptual approaches facilitating the design and deliberate construction of metal–organic frameworks (MOFs), namely supermolecular building block (SBB) and supermolecular building layer (SBL) approaches. Our main objective is to offer an appropriate means to assist/aid chemists and material designers alike to rationally construct desired functional MOF materials, made-to-order MOFs. We introduce the concept of net-coded building units (net-cBUs), where precise embedded geometrical information codes uniquely and matchlessly a selected net, as a compelling route for the rational design of MOFs. This concept is based on employing pre-selected 0-periodic metal–organic polyhedra or 2-periodic metal–organic layers, SBBs or SBLs respectively, as a pathway to access the requisite net-cBUs. In this review, inspired by our success with the original rht-MOF, we extrapolated our strategy to other known MOFs via their deconstruction into more elaborate building units (namely polyhedra or layers) to (i) elucidate the unique relationship between edge-transitive polyhedra or layers and minimal edge-transitive 3-periodic nets, and (ii) illustrate the potential of the SBB and SBL approaches as a rational pathway for the design and construction of 3-periodic MOFs. Using this design strategy, we have also identified several new hypothetical MOFs which are synthetically targetable.en
dc.publisherRoyal Society of Chemistryen
dc.relation.urlhttp://xlink.rsc.org/?DOI=C4CS00135Den
dc.rightsArchived with thanks to Chem. Soc. Rev. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. http://creativecommons.org/licenses/by-nc/3.0/en
dc.titleA supermolecular building approach for the design and construction of metal–organic frameworksen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Centeren
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalChem. Soc. Rev.en
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionDepartment of Chemistry, Ulsan National Institute of Science and Technology, Ulsan, Koreaen
dc.contributor.institutionDepartment of Chemistry and Physics, Florida Southern College, Lakeland, USAen
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, USAen
kaust.authorGuillerm, Vincenten
kaust.authorLuebke, Ryanen
kaust.authorAdil, Karimen
kaust.authorEddaoudi, Mohameden
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