C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex

Handle URI:
http://hdl.handle.net/10754/550320
Title:
C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex
Authors:
Huang, Kuo-Wei ( 0000-0003-1900-2658 ) ; Wang, Yuan; Zheng, Bin; Pan, Yupeng; Pan, Chengling; He, Lipeng
Abstract:
A neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
C-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex 2015 Dalton Trans.
Publisher:
Royal Society of Chemistry (RSC)
Journal:
Dalton Trans.
Issue Date:
13-Apr-2015
DOI:
10.1039/C5DT00787A
Type:
Article
ISSN:
1477-9226; 1477-9234
Is Supplemented By:
Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050930: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148kzy; DOI:10.5517/cc148kzy; HANDLE:http://hdl.handle.net/10754/624414; Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050931: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l00; DOI:10.5517/cc148l00; HANDLE:http://hdl.handle.net/10754/624415; Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l11; DOI:10.5517/cc148l11; HANDLE:http://hdl.handle.net/10754/624416; Wang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l22; DOI:10.5517/cc148l22; HANDLE:http://hdl.handle.net/10754/624417
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT00787A
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorHuang, Kuo-Weien
dc.contributor.authorWang, Yuanen
dc.contributor.authorZheng, Binen
dc.contributor.authorPan, Yupengen
dc.contributor.authorPan, Chenglingen
dc.contributor.authorHe, Lipengen
dc.date.accessioned2015-04-19T11:10:37Zen
dc.date.available2015-04-19T11:10:37Zen
dc.date.issued2015-04-13en
dc.identifier.citationC-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complex 2015 Dalton Trans.en
dc.identifier.issn1477-9226en
dc.identifier.issn1477-9234en
dc.identifier.doi10.1039/C5DT00787Aen
dc.identifier.urihttp://hdl.handle.net/10754/550320en
dc.description.abstractA neutral complex PN3P-Rh(I)Cl (2) was prepared from a reaction of the PN3P pincer ligand (1) with [Rh(COD)Cl]2 (COD = 1,5-cyclooctadiene). Upon treatment with a suitable base, H–H and Csp2–H activation reactions can be achieved through the deprotonation/reprotonation of one of the N–H arms and dearomatization/rearomatization of the central pyridine ring with the oxidation state of Rh remaining I.en
dc.publisherRoyal Society of Chemistry (RSC)en
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/DT/C5DT00787Aen
dc.rightsDOI: 10.1039/C5DT00787Aen
dc.titleC-H and H-H Bond Activation via Ligand Dearomatization/Rearomatization of a PN3P-Rhodium(I) Complexen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalDalton Trans.en
dc.eprint.versionPost-printen
kaust.authorHe, Lipengen
kaust.authorHuang, Kuo-Weien
kaust.authorWang, Yuanen
kaust.authorZheng, Binen
kaust.authorPan, Yupengen
kaust.authorPan, Chenglingen
dc.relation.isSupplementedByWang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050930: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148kzyen
dc.relation.isSupplementedByDOI:10.5517/cc148kzyen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624414en
dc.relation.isSupplementedByWang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050931: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l00en
dc.relation.isSupplementedByDOI:10.5517/cc148l00en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624415en
dc.relation.isSupplementedByWang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050932: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l11en
dc.relation.isSupplementedByDOI:10.5517/cc148l11en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624416en
dc.relation.isSupplementedByWang, Y., Zheng, B., Pan, Y., Pan, C., He, L., & Huang, K.-W. (2015). CCDC 1050933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc148l22en
dc.relation.isSupplementedByDOI:10.5517/cc148l22en
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624417en
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