Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures

Handle URI:
http://hdl.handle.net/10754/550073
Title:
Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures
Authors:
Zhang, Zhen; Zhang, Hefeng; Gnanou, Yves ( 0000-0001-6253-7856 ) ; Hadjichristidis, Nikolaos ( 0000-0003-1442-1714 )
Abstract:
A novel strategy, based on the in situ generated Boron-thexyl-silaboracyclic initiating sites for the polyhomologation of dimethylsulfoxonium methylide, has been developed for the synthesis of complex polyethylene-based architectures. As examples, the synthesis of a 4-arm polyethylene star, three (polystyrene)(polyethylene)2 3-miktoarm stars and a PE-branched double graft copolymers are given.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC); Polymer Synthesis Laboratory
Citation:
Hadjichristidis, Nikos, Zhen Zhang, and Yves Gnanou. "Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures." Chemical Communications (2015).
Publisher:
Royal Society of Chemistry
Journal:
Chem. Commun.
Issue Date:
10-Apr-2015
DOI:
10.1039/C5CC01579K
Type:
Article
ISSN:
1359-7345; 1364-548X
Additional Links:
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC01579K
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorZhang, Zhenen
dc.contributor.authorZhang, Hefengen
dc.contributor.authorGnanou, Yvesen
dc.contributor.authorHadjichristidis, Nikolaosen
dc.date.accessioned2015-04-14T12:42:10Zen
dc.date.available2015-04-14T12:42:10Zen
dc.date.issued2015-04-10en
dc.identifier.citationHadjichristidis, Nikos, Zhen Zhang, and Yves Gnanou. "Polyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architectures." Chemical Communications (2015).en
dc.identifier.issn1359-7345en
dc.identifier.issn1364-548Xen
dc.identifier.doi10.1039/C5CC01579Ken
dc.identifier.urihttp://hdl.handle.net/10754/550073en
dc.description.abstractA novel strategy, based on the in situ generated Boron-thexyl-silaboracyclic initiating sites for the polyhomologation of dimethylsulfoxonium methylide, has been developed for the synthesis of complex polyethylene-based architectures. As examples, the synthesis of a 4-arm polyethylene star, three (polystyrene)(polyethylene)2 3-miktoarm stars and a PE-branched double graft copolymers are given.en
dc.publisherRoyal Society of Chemistryen
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC01579Ken
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/en
dc.titlePolyhomologation based on in situ generated Boron-thexyl-silaboracyclic initiating sites: a novel strategy towards the synthesis of polyethylene-based complex architecturesen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPolymer Synthesis Laboratoryen
dc.identifier.journalChem. Commun.en
dc.eprint.versionPublisher's Version/PDFen
kaust.authorZhang, Hefengen
kaust.authorGnanou, Yvesen
kaust.authorHadjichristidis, Nikolaosen
kaust.authorZhang, Zhenen
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