Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

Handle URI:
http://hdl.handle.net/10754/347339
Title:
Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
Authors:
Manzini, Simone; Urbina Blanco, César A.; Nelson, David J.; Poater, Albert; Lebl, Tomas; Meiries, Sébastien; Slawin, Alexandra M.Z.; Falivene, Laura ( 0000-0003-1509-6191 ) ; Cavallo, Luigi ( 0000-0002-1398-338X ) ; Nolan, Steven P.
Abstract:
The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.
KAUST Department:
Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)
Citation:
Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene 2015, 780:43 Journal of Organometallic Chemistry
Publisher:
Elsevier BV
Journal:
Journal of Organometallic Chemistry
Issue Date:
Mar-2015
DOI:
10.1016/j.jorganchem.2014.12.040
Type:
Article
ISSN:
0022328X
Is Supplemented By:
Manzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999049: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jldl; DOI:10.5517/cc12jldl; HANDLE:http://hdl.handle.net/10754/624315; Manzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999050: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jlfm; DOI:10.5517/cc12jlfm; HANDLE:http://hdl.handle.net/10754/624316
Additional Links:
http://linkinghub.elsevier.com/retrieve/pii/S0022328X15000066
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorManzini, Simoneen
dc.contributor.authorUrbina Blanco, César A.en
dc.contributor.authorNelson, David J.en
dc.contributor.authorPoater, Alberten
dc.contributor.authorLebl, Tomasen
dc.contributor.authorMeiries, Sébastienen
dc.contributor.authorSlawin, Alexandra M.Z.en
dc.contributor.authorFalivene, Lauraen
dc.contributor.authorCavallo, Luigien
dc.contributor.authorNolan, Steven P.en
dc.date.accessioned2015-03-31T06:12:49Zen
dc.date.available2015-03-31T06:12:49Zen
dc.date.issued2015-03en
dc.identifier.citationEvaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene 2015, 780:43 Journal of Organometallic Chemistryen
dc.identifier.issn0022328Xen
dc.identifier.doi10.1016/j.jorganchem.2014.12.040en
dc.identifier.urihttp://hdl.handle.net/10754/347339en
dc.description.abstractThe commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored.en
dc.publisherElsevier BVen
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S0022328X15000066en
dc.rightsArchived with thanks to Journal of Organometallic Chemistry. Copyright © 2015 Elsevier B.V. All rights reserved.en
dc.titleEvaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbeneen
dc.typeArticleen
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.identifier.journalJournal of Organometallic Chemistryen
dc.eprint.versionPost-printen
dc.contributor.institutionEaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife, KY16 9ST, UKen
dc.contributor.institutionInstitut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spainen
dc.contributor.institutionDepartment of Chemistry and Biology, University of Salerno, Via Ponte don Melillo, Fisciano I-84084, Italyen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorFalivene, Lauraen
kaust.authorCavallo, Luigien
dc.relation.isSupplementedByManzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999049: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jldlen
dc.relation.isSupplementedByDOI:10.5517/cc12jldlen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624315en
dc.relation.isSupplementedByManzini, S., Blanco, C. A. U., Nelson, D. J., Poater, A., Lebl, T., Meiries, S., … Nolan, S. P. (2015). CCDC 999050: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc12jlfmen
dc.relation.isSupplementedByDOI:10.5517/cc12jlfmen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624316en
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