A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

Handle URI:
http://hdl.handle.net/10754/347290
Title:
A new class of PN3-pincer ligands for metal–ligand cooperative catalysis
Authors:
Li, Huaifeng ( 0000-0001-9661-803X ) ; Zheng, Bin; Huang, Kuo-Wei ( 0000-0003-1900-2658 )
Abstract:
Work on a new class of PN3-pincer ligands for metal-ligand cooperative catalysis is reviewed. While the field of the pyridine-based PN3-transition metal pincer complexes is still relatively young, many important applications of these complexes have already emerged. In several cases, the PN3-pincer complexes for metal-ligand cooperative catalysis result in significantly improved or unprecedented activities. The synthesis and coordination chemistry of PN3-pincer ligands are briefly summarized first to cover the synthetic routes for their preparation, followed by a focus review on their applications in catalysis. A specific emphasis is placed on the later section about the role of PN3-pincer ligands' dearomatization-rearomatization steps during the catalytic cycles. The mechanistic insights from density functional theory (DFT) calculations are also discussed.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
A new class of PN3-pincer ligands for metal–ligand cooperative catalysis 2014 Coordination Chemistry Reviews
Publisher:
Elsevier
Journal:
Coordination Chemistry Reviews
Issue Date:
Dec-2014
DOI:
10.1016/j.ccr.2014.11.010
Type:
Article
ISSN:
00108545
Additional Links:
http://linkinghub.elsevier.com/retrieve/pii/S0010854514003300
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorLi, Huaifengen
dc.contributor.authorZheng, Binen
dc.contributor.authorHuang, Kuo-Weien
dc.date.accessioned2015-03-30T12:53:35Zen
dc.date.available2015-03-30T12:53:35Zen
dc.date.issued2014-12en
dc.identifier.citationA new class of PN3-pincer ligands for metal–ligand cooperative catalysis 2014 Coordination Chemistry Reviewsen
dc.identifier.issn00108545en
dc.identifier.doi10.1016/j.ccr.2014.11.010en
dc.identifier.urihttp://hdl.handle.net/10754/347290en
dc.description.abstractWork on a new class of PN3-pincer ligands for metal-ligand cooperative catalysis is reviewed. While the field of the pyridine-based PN3-transition metal pincer complexes is still relatively young, many important applications of these complexes have already emerged. In several cases, the PN3-pincer complexes for metal-ligand cooperative catalysis result in significantly improved or unprecedented activities. The synthesis and coordination chemistry of PN3-pincer ligands are briefly summarized first to cover the synthetic routes for their preparation, followed by a focus review on their applications in catalysis. A specific emphasis is placed on the later section about the role of PN3-pincer ligands' dearomatization-rearomatization steps during the catalytic cycles. The mechanistic insights from density functional theory (DFT) calculations are also discussed.en
dc.publisherElsevieren
dc.relation.urlhttp://linkinghub.elsevier.com/retrieve/pii/S0010854514003300en
dc.rightsArchived with thanks to Coordination Chemistry Reviews. Copyright © 2014 Elsevier B.V. All rights reserved.en
dc.titleA new class of PN3-pincer ligands for metal–ligand cooperative catalysisen
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalCoordination Chemistry Reviewsen
dc.eprint.versionPost-printen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorLi, Huaifengen
kaust.authorZheng, Binen
kaust.authorHuang, Kuo-Weien
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