Ammonia Synthesis using Ti and Nb Nitride Nano-particles Prepared by Mesoporous Graphitic C3N4

Handle URI:
http://hdl.handle.net/10754/344118
Title:
Ammonia Synthesis using Ti and Nb Nitride Nano-particles Prepared by Mesoporous Graphitic C3N4
Authors:
Kumagai, Hiromu; Takanabe, Kazuhiro ( 0000-0001-5374-9451 ) ; Kubota, Jun; Domen, Kazunari
Abstract:
TiN and NbN nanoparticles were synthesized from mesoporous graphitic C3N4 (mpg-C3N4) as a reactive template and used as the catalyst for ammonia synthesis. The obtained TiN and NbN nanoparticles possess high surface areas of 299 and 275 m2 g-1, respectively, making them attractive in the use of catalysis and support. Although most of the TiN and NbN particles show no measurable activity for ammonia formation, the nanoparticles enabled an ammonia synthesis rate of 31 μmol h-1 g-cat-1 at 673 K and 0.1 MPa of synthesis gas (N2 + 3H2) for both TiN and NbN catalysts. It is evident that the formation of nanoparticles with high nitride surface area is essential for the materials to function as catalysts in ammonia synthesis. The addition of Fe to TiN enhanced the ammonia synthesis activity, whereas it had detrimental effects on the catalytic activity of NbN. The properties of these catalysts in ammonia synthesis are discussed.
KAUST Department:
KAUST Catalysis Center (KCC); Physical Sciences and Engineering (PSE) Division
Citation:
Kumagai, H., Takanabe, K., Kubota, J., & Domen, K. (2015). Ammonia Synthesis using Ti and Nb Nitride Nano-particles Prepared by Mesoporous Graphitic C3N4. Bulletin of the Chemical Society of Japan, advpub. doi: 10.1246/bcsj.20140395
Publisher:
The Chemical Society of Japan
Journal:
Bulletin of the Chemical Society of Japan
Issue Date:
22-Jan-2015
DOI:
10.1246/bcsj.20140395
Type:
Article
ISSN:
0009-2673; 1348-0634
Sponsors:
This work is partly supported by CREST of Japan Science and Technology Agency (JST) named as Creation of Innovative Core Technology for Manufacture and Use of Energy Carriers from Renewable Energy, and also partly supported by the King Abdullah University of Science and Technology. This work is contributed to the international exchange program Japan Society for the Promotion of Science (JSPS) named as A3 Foresight Program. The authors are grateful to N.S. Alhajri at KAUST for her assistance in operating SEM and TEM.
Additional Links:
https://www.jstage.jst.go.jp/article/bcsj/advpub/0/advpub_20140395/_article
Appears in Collections:
Articles; Physical Sciences and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

Full metadata record

DC FieldValue Language
dc.contributor.authorKumagai, Hiromuen
dc.contributor.authorTakanabe, Kazuhiroen
dc.contributor.authorKubota, Junen
dc.contributor.authorDomen, Kazunarien
dc.date.accessioned2015-02-04T06:48:21Z-
dc.date.available2015-02-04T06:48:21Z-
dc.date.issued2015-01-22en
dc.identifier.citationKumagai, H., Takanabe, K., Kubota, J., & Domen, K. (2015). Ammonia Synthesis using Ti and Nb Nitride Nano-particles Prepared by Mesoporous Graphitic C3N4. Bulletin of the Chemical Society of Japan, advpub. doi: 10.1246/bcsj.20140395en
dc.identifier.issn0009-2673en
dc.identifier.issn1348-0634en
dc.identifier.doi10.1246/bcsj.20140395en
dc.identifier.urihttp://hdl.handle.net/10754/344118en
dc.description.abstractTiN and NbN nanoparticles were synthesized from mesoporous graphitic C3N4 (mpg-C3N4) as a reactive template and used as the catalyst for ammonia synthesis. The obtained TiN and NbN nanoparticles possess high surface areas of 299 and 275 m2 g-1, respectively, making them attractive in the use of catalysis and support. Although most of the TiN and NbN particles show no measurable activity for ammonia formation, the nanoparticles enabled an ammonia synthesis rate of 31 μmol h-1 g-cat-1 at 673 K and 0.1 MPa of synthesis gas (N2 + 3H2) for both TiN and NbN catalysts. It is evident that the formation of nanoparticles with high nitride surface area is essential for the materials to function as catalysts in ammonia synthesis. The addition of Fe to TiN enhanced the ammonia synthesis activity, whereas it had detrimental effects on the catalytic activity of NbN. The properties of these catalysts in ammonia synthesis are discussed.en
dc.description.sponsorshipThis work is partly supported by CREST of Japan Science and Technology Agency (JST) named as Creation of Innovative Core Technology for Manufacture and Use of Energy Carriers from Renewable Energy, and also partly supported by the King Abdullah University of Science and Technology. This work is contributed to the international exchange program Japan Society for the Promotion of Science (JSPS) named as A3 Foresight Program. The authors are grateful to N.S. Alhajri at KAUST for her assistance in operating SEM and TEM.en
dc.language.isoenen
dc.publisherThe Chemical Society of Japanen
dc.relation.urlhttps://www.jstage.jst.go.jp/article/bcsj/advpub/0/advpub_20140395/_articleen
dc.rightsArchived with thanks to Bulletin of the Chemical Society of Japanen
dc.titleAmmonia Synthesis using Ti and Nb Nitride Nano-particles Prepared by Mesoporous Graphitic C3N4en
dc.typeArticleen
dc.contributor.departmentKAUST Catalysis Center (KCC)en
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Divisionen
dc.identifier.journalBulletin of the Chemical Society of Japanen
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionDepartment of Chemical System Engineering, The University of Tokyoen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorTakanabe, Kazuhiroen
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