Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture

Handle URI:
http://hdl.handle.net/10754/325335
Title:
Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture
Authors:
Shekhah, Osama ( 0000-0003-1861-9226 ) ; Belmabkhout, Youssef ( 0000-0001-9952-5007 ) ; Chen, Zhijie; Guillerm, Vincent ( 0000-0003-3460-223X ) ; Cairns, Amy; Adil, Karim ( 0000-0002-3804-1065 ) ; Eddaoudi, Mohamed ( 0000-0003-1916-9837 )
Abstract:
Direct air capture is regarded as a plausible alternate approach that, if economically practical, can mitigate the increasing carbon dioxide emissions associated with two of the main carbon polluting sources, namely stationary power plants and transportation. Here we show that metal-organic framework crystal chemistry permits the construction of an isostructural metal-organic framework (SIFSIX-3-Cu) based on pyrazine/copper(II) two-dimensional periodic 4 4 square grids pillared by silicon hexafluoride anions and thus allows further contraction of the pore system to 3.5 versus 3.84 for the parent zinc(II) derivative. This enhances the adsorption energetics and subsequently displays carbon dioxide uptake and selectivity at very low partial pressures relevant to air capture and trace carbon dioxide removal. The resultant SIFSIX-3-Cu exhibits uniformly distributed adsorption energetics and offers enhanced carbon dioxide physical adsorption properties, uptake and selectivity in highly diluted gas streams, a performance, to the best of our knowledge, unachievable with other classes of porous materials. 2014 Macmillan Publishers Limited.
KAUST Department:
Functional Materials Design, Discovery and Development (FMD3)
Citation:
Shekhah O, Belmabkhout Y, Chen Z, Guillerm V, Cairns A, et al. (2014) Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture. Nature Communications 5. doi:10.1038/ncomms5228.
Publisher:
Nature Publishing Group
Journal:
Nature Communications
Issue Date:
25-Jun-2014
DOI:
10.1038/ncomms5228
PubMed ID:
24964404
PubMed Central ID:
PMC4083436
Type:
Article
ISSN:
20411723
Is Supplemented By:
Shekhah, O., Belmabkhout, Y., Chen, Z., Guillerm, V., Cairns, A., Adil, K., & Eddaoudi, M. (2014). CCDC 970790: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11l5tm; DOI:10.5517/cc11l5tm; HANDLE:http://hdl.handle.net/10754/624282
Appears in Collections:
Articles; Functional Materials Design, Discovery and Development (FMD3)

Full metadata record

DC FieldValue Language
dc.contributor.authorShekhah, Osamaen
dc.contributor.authorBelmabkhout, Youssefen
dc.contributor.authorChen, Zhijieen
dc.contributor.authorGuillerm, Vincenten
dc.contributor.authorCairns, Amyen
dc.contributor.authorAdil, Karimen
dc.contributor.authorEddaoudi, Mohameden
dc.date.accessioned2014-08-27T09:47:36Z-
dc.date.available2014-08-27T09:47:36Z-
dc.date.issued2014-06-25en
dc.identifier.citationShekhah O, Belmabkhout Y, Chen Z, Guillerm V, Cairns A, et al. (2014) Made-to-order metal-organic frameworks for trace carbon dioxide removal and air capture. Nature Communications 5. doi:10.1038/ncomms5228.en
dc.identifier.issn20411723en
dc.identifier.pmid24964404en
dc.identifier.doi10.1038/ncomms5228en
dc.identifier.urihttp://hdl.handle.net/10754/325335en
dc.description.abstractDirect air capture is regarded as a plausible alternate approach that, if economically practical, can mitigate the increasing carbon dioxide emissions associated with two of the main carbon polluting sources, namely stationary power plants and transportation. Here we show that metal-organic framework crystal chemistry permits the construction of an isostructural metal-organic framework (SIFSIX-3-Cu) based on pyrazine/copper(II) two-dimensional periodic 4 4 square grids pillared by silicon hexafluoride anions and thus allows further contraction of the pore system to 3.5 versus 3.84 for the parent zinc(II) derivative. This enhances the adsorption energetics and subsequently displays carbon dioxide uptake and selectivity at very low partial pressures relevant to air capture and trace carbon dioxide removal. The resultant SIFSIX-3-Cu exhibits uniformly distributed adsorption energetics and offers enhanced carbon dioxide physical adsorption properties, uptake and selectivity in highly diluted gas streams, a performance, to the best of our knowledge, unachievable with other classes of porous materials. 2014 Macmillan Publishers Limited.en
dc.language.isoenen
dc.publisherNature Publishing Groupen
dc.rightsThis work is licensed under a Creative Commons License.en
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/en
dc.subjectcarbon dioxideen
dc.subjectcupric ionen
dc.subjectmetal organic frameworken
dc.subjectmethanolen
dc.subjectpyrazineen
dc.subjectsiliconen
dc.subjectunclassified drugen
dc.subjectzincen
dc.subjectzinc(ii)en
dc.subjectadsorptionen
dc.subjectadsorption kineticsen
dc.subjectairen
dc.subjectcomparative studyen
dc.subjectcontrolled studyen
dc.subjectcrystal structureen
dc.subjectdesorptionen
dc.subjectenergy transferen
dc.subjecthypobarismen
dc.subjectisothermen
dc.subjectporosityen
dc.subjectthermogravimetryen
dc.subjectX ray crystallographyen
dc.subjectX ray diffractionen
dc.titleMade-to-order metal-organic frameworks for trace carbon dioxide removal and air captureen
dc.typeArticleen
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)en
dc.identifier.journalNature Communicationsen
dc.identifier.pmcidPMC4083436en
dc.eprint.versionPublisher's Version/PDFen
dc.contributor.institutionUnidad Académica de Sistemas Arrecifales (Puerto Morelos), Instituto de Ciencias Del Mar y Limnología, Universidad Nacional Autõnoma de México, Puerto Morelos, QR 77580, Mexicoen
dc.contributor.institutionSchool of Natural Sciences, University of California Merced, 5200 North Lake Road, Merced, CA 95343, United Statesen
dc.contributor.affiliationKing Abdullah University of Science and Technology (KAUST)en
kaust.authorShekhah, Osamaen
kaust.authorBelmabkhout, Youssefen
kaust.authorGuillerm, Vincenten
kaust.authorCairns, Amyen
kaust.authorAdil, Karimen
kaust.authorEddaoudi, Mohameden
kaust.authorChen, Zhijieen
dc.relation.isSupplementedByShekhah, O., Belmabkhout, Y., Chen, Z., Guillerm, V., Cairns, A., Adil, K., & Eddaoudi, M. (2014). CCDC 970790: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11l5tmen
dc.relation.isSupplementedByDOI:10.5517/cc11l5tmen
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624282en

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